Chromeless phase-shifting mask for equal line/space dense line patterns

ABSTRACT

A phase-shifting mask suited for equal line/space, small pitched, dense line pattern is disclosed. The phase-shifting mask includes a transparent substrate, a partially shielded mesa line pattern of first phase formed on the substrate, and a clear recessed line pattern of second phase etched into the substrate and is disposed right next to the partially shielded mesa line pattern. The partially shielded mesa line pattern has a plurality of alternating 5%-10% transmittance light-shielding regions and clear regions of the first phase. The partially shielded mesa line pattern and the clear recessed line pattern have the same line width. The light that passes through the clear regions of the first phase and the light that passes through the clear recessed line pattern of second phase have a phase difference of 180 degree.

BACKGROUND OF INVENTION

1. Field of the Invention

The present invention relates to a phase-shifting mask (PSM), and more particularly, to a chromeless PSM for equal line/space dense line patterns and lithographic method of employing such chromeless PSM.

2. Description of the Prior Art

Lithography processing, which is an essential technology when manufacturing conventional integrated circuits, is used for defining geometries, features, lines, or shapes onto a die or wafer. In the integrated circuit making processes, lithography plays an important role in limiting feature size. By using lithography, a circuit pattern can be precisely transferred onto a die or wafer. Typically, to implement the lithography, a designed pattern such as a circuit layout pattern or an ion doping layout pattern in accordance with a predetermined design rule is created on one or several mask in advance. The pattern on the mask is then transferred by light exposure, with a stepper and scanner, onto the wafer.

It is critical in this field to solve resolution of the lithographic process as the device sizes of the semiconductor industry continue to shrink to the deep sub-micron scale. There are primarily two methods in the prior art for improving resolution. One method involves using short wavelengths of light to expose a photoresist layer on the semiconductor wafer. Short wavelengths of light are desirable as the shorter the wavelength, the higher the possible resolution of the pattern. Another method involves the use of a phase-shifting mask (PSM) to improve the resolution of the pattern transferred to the semiconductor wafer.

Please refer to FIG. 1, which is a structural diagram of a prior art alternating phase-shifting mask 10. As shown in FIG. 1, a fully opaque material such as chrome is used in a non-transparent region 12 of the alternating phase-shifting mask 10, and the non-transparent region 12 is flanked by transparent regions 14, 16. Both of the transparent regions 14, 16 are made of quartz. The thickness of the transparent region 14 is less than that of the transparent region 16. Therefore, light that passes through the transparent region 14 has a 180-degree phase shift relative to light that passes through the thicker transparent region 16, which results in destructive interference and image contrast. Consequently, during the lithographic process, a dark unexposed region falls on an area of a photoresist layer and is located below the non-transparent region 12 of the alternating phase-shifting mask 10.

However, the alternating phase-shifting mask (alt-PSM) 10 has to perform a double-exposure/two-mask lithography process involving a trim mask to complete pattern transferring. The first mask is a phase-shifting mask and the second mask is a single-phase trim mask. The phase-shifting mask primarily defines regions requiring phase shifting. The single-phase trim mask primarily defines regions not requiring phase shifting. However, this optical proximity correction (OPC) technique suffers from transmission imbalance occurred in phase shifted and non-phase-shifted regions and other flaws caused by alt-PSM.

Therefore, a chromeless phase-shifting mask is developed. Please refer to FIG. 2, which is a structural diagram of a prior art chromeless phase-shifting mask 20. As shown in FIG. 2, the chromeless phase-shifting mask comprises a transparent region 22 made of quartz, and the transparent region 22 is flanked by two transparent regions 24, 26 also made of quartz. The transparent region 22 is thicker than both the transparent regions 24, 26, which causes a 180 degree phase-shifting in light passing through the transparent regions 24, 26.

In other words, the transparent regions 24, 26 are phase-shifting regions, and the transparent region 22 is a non-phase-shifting region. Because of this 180-degree phase difference, there is destructive interference at the phase boundaries of the phase-shifting regions 24, 26 and the non-phase-shifting region 22. Consequently, during the lithographic process, a dark unexposed region falls on an area of a photoresist layer and is located below the non-phase-shifting region 22 of the chromeless phase-shifting mask 20.

However, with the increase of packing density of devices such as dynamic random access memory (DRAM) devices, a pitch between adjacent micro features of the device such as word line pitch shrinks dramatically. Please refer to FIG. 3. FIG. 3 is a plan view of a portion of word lines 32 overlying a semiconductor wafer 30. As shown in FIG. 3, pitch P of the word lines 32 is equal to the combination of line width L and the spacing S between two adjacent word lines 32 (P=L+S). When the line width L is less than or equal to 100 nm, and the pitch P is substantially equal to the twice of the line width L of the device and forms a dense pattern, light of 0 degree phase-shifting and light of 180 degrees phase-shifting cancel out. Therefore, the prior art chromeless phase-shifting mask fails to transfer the dense pattern.

SUMMARY OF INVENTION

It is therefore an object of the claimed invention to provide a chromeless phase-shifting mask for solving the above-mentioned problems.

According to the claimed invention, a chromeless PSM for forming equal line/space, small pitched, dense line pattern is disclosed. The chromeless PSM includes a transparent substrate, a partially shielded mesa line pattern of first phase formed on the substrate, and a clear recessed line pattern of second phase etched into the substrate and is disposed right next to the partially shielded mesa line pattern. The partially shielded mesa line pattern has a plurality of alternating 5%-10% transmittance light-shielding regions and clear regions of the first phase. The partially shielded mesa line pattern and the clear recessed line pattern have the same line width. The light that passes through the clear regions of the first phase and the light that passes through the clear recessed line pattern of second phase have a phase difference of 180 degree.

From one aspect of this invention, a chromeless PSM comprises a transparent substrate; a plurality of first phase-shifting line patterns having a first substrate thickness of first phase disposed on the transparent substrate along a first direction, wherein each of the first phase-shifting line patterns is disposed thereon clear regions of the first phase and 5%-10% light transmittable block areas. A plurality of 100% light transmittable second phase-shifting line patterns, in parallel with the first phase-shifting line patterns, has a second substrate thickness of second phase. The first phase-shifting line patterns and second phase-shifting line patterns have the same line width and are alternately disposed on the transparent substrate.

These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment that is illustrated in the various figures and drawings.

BRIEF DESCRIPTION OF DRAWINGS

The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention. In the drawings:

FIG. 1 is a structural diagram of a prior art alternating phase mask;

FIG. 2 is a structural diagram of a prior art chromeless phase-shifting mask;

FIG. 3 is a plan view of a portion of word lines overlying a semiconductor wafer;

FIG. 4 is a plan view of a portion of the layout of a chromeless PSM in accordance with one preferred embodiment of this invention;

FIG. 5 is a schematic, cross-sectional view of the chromeless PSM taken along line I-I of FIG. 4;

FIG. 6 is a schematic, cross-sectional view of the chromeless PSM taken along line II-II of FIG. 4;

FIG. 7 is a plan view of a portion of the resultant equal line/space dense line pattern transferred from the chromeless PSM of this invention to a photoresist film coated on a wafer;

FIG. 8 is a schematic diagram illustrating the CD uniformity of the equal line/space dense line patterns 202 a and 202 b of FIG. 7 according to the first preferred embodiment of this invention;

FIG. 9 is a plan view of a portion of the layout of a chromeless PSM in accordance with second preferred embodiment of this invention;

FIG. 10 is a schematic, cross-sectional view of the chromeless PSM taken along line I-I of FIG. 9;

FIG. 11 is a schematic, cross-sectional view of the chromeless PSM taken along line II-II of FIG. 9;

FIG. 12 is a plan view of a portion of the resultant equal line/space dense line pattern transferred from the chromeless PSM of FIG. 9 to a photoresist film in accordance with the second embodiment of this invention; and

FIG. 13 is a schematic diagram illustrating the CD uniformity of the equal line/space dense line patterns 202 a and 202 b of FIG. 12 according to the second preferred embodiment of this invention.

DETAILED DESCRIPTION

In describing the preferred embodiment of the present invention, reference will be made herein to FIGS. 4-13 of the drawings, wherein like numerals designate like components, areas or regions. Features of the invention are not drawn to scale in the drawings.

The present invention pertains to an improved chromeless phase-shifting mask (PSM), which is capable of solving equal line/space, small pitched, dense line patterns such as word lines or gate conductors of trench-capacitor dynamic random access memory (DRAM) devices having critical line width that is less than or equal to 100 nanometers. The critical dimension (CD) uniformity of the resultant equal line/space dense line pattern transferred from the chromeless PSM of this invention to a photoresist film coated on a wafer is also enhanced.

Please refer to FIGS. 4-7, wherein FIG. 4 is a plan view of a portion of the layout of a chromeless PSM in accordance with one preferred embodiment of this invention; FIG. 5 is a schematic, cross-sectional view of the chromeless PSM taken along line I-I of FIG. 4; FIG. 6 is a schematic, cross-sectional view of the chromeless PSM taken along line II-II of FIG. 4; FIG. 7 is a plan view of a portion of the resultant equal line/space dense line pattern transferred from the chromeless PSM of this invention to a photoresist film coated on a wafer.

As shown in FIG. 4, the chromeless PSM in accordance with one preferred embodiment of this invention comprises a transparent quartz substrate 100, a plurality of first phase-shifting line patterns 102 a-102 f arranged in parallel with each other along the reference Y-axis, and a plurality of second phase-shifting line patterns 104 a-104 e arranged in parallel with each other along the reference Y-axis. According to the preferred embodiment, the line width of each of the first phase-shifting line patterns 102 a-102 f and the line width of each of the second phase-shifting line patterns 104 a-104 e are the same.

The aforesaid first phase-shifting line patterns 102 a-102 f and second phase-shifting line patterns 104 a-104 e are alternately formed on the quartz substrate 100. By way of example, the second phase-shifting line pattern 104 a is disposed between the first phase-shifting line pattern 102 a and the first phase-shifting line pattern 102 b, the second phase-shifting line pattern 104 b is disposed between the first phase-shifting line pattern 102 b and the first phase-shifting line pattern 102 c, and so forth. Besides, along each of the first phase-shifting line patterns 102 a-102 f, a plurality of block areas 106 a-106 f are provided. The block areas are disposed spaced apart from each other along each of first phase-shifting line patterns 102 a-102 f. As shown in FIG. 4, for example, a 100%-light transmission first phase-shifting area 108 a is disposed between two adjacent block areas 106 a along the first phase-shifting line pattern 102 a. The block areas are equal in size and have a light transmission rate of about 5%-10%, i.e., merely 5%-10% of the incident light can pass through each of the block areas.

According to the first preferred embodiment, each of the block areas 106 a-106 f is masked by a phase shifter such as MoSi, MoSiO, MoSiON or the like.

Therefore, the second phase-shifting line patterns 104 a-104 e of the chromeless PSM of this invention are 100% light transmittable. Each of the first phase-shifting line patterns 102 a-102 f of the chromeless PSM encompasses alternating 100% light transmittable clear areas and 5%-10% light transmittable block areas. The phase-shifting mask of this invention is partially shielded along the mesa line pattern 102 a-102 f of first phase. According to the first preferred embodiment, the length of one side of each of the rectangular 5%-10% light transmittable block areas 106 a-106 f along the reference Y-axis ranges approximately from λ/4 to 3λ/4 (λ: wavelength of the exposure light source of the stepper and scanner, in nanometer). The length of one side of each of the rectangular 100% light transmittable clear areas 108 a-108 f along the reference Y-axis ranges approximately from λ/4 to 3λ/4.

As shown in FIG. 5 and FIG. 6, the thickness of the quartz substrate 100 underneath each of the first phase-shifting line patterns 102 a-102 f is denoted as t₁, and the thickness of the quartz substrate 100 underneath each of the second phase-shifting line patterns (also referred to as “clear recessed line patterns”) 104 a-104 e is denoted as t₂, wherein t₁is greater than t₂(t₁>t₂), such that light passing through the quartz substrate 100 having different thicknesses produces image contrast. The phase difference between the phase of light passed through the first phase-shifting line patterns 102 a-102 f and the phase of light passed through the second phase-shifting line patterns 104 a-104 e is 180 degree. Preferably, the phase of light passed through the first phase-shifting line patterns 102 a-102 f is 0-degree, while the phase of light passed through the second phase-shifting line patterns 104 a-104 e is 180-degree (π).

According to the first preferred embodiment, the plurality of spaced apart 5%-10% light transmittable block areas 106 a-106 f, which are disposed on each of the first phase-shifting line patterns 102 a-102 f, are aligned with the reference X-axis. By providing such unique layout of the chromeless PSM, resultant dense line patterns 202 a-202 f transferred from the chromeless PSM of this invention to a photoresist film coated on a wafer is depicted in FIG. 7. However, the critical dimension (CD) uniformity of the resultant dense line pattern (in equal line/space fashion) is still not satisfactory.

Please refer to FIG. 8. FIG. 8 is a schematic diagram illustrating the CD uniformity of the equal line/space dense line patterns 202 a and 202 b of FIG. 7 according to the first preferred embodiment of this invention. As can be seen in this figure, the variation of the CD of the line pattern 202 a or 202 b is high, and leads to wavelike line profiles.

Please refer to FIGS. 9-12, wherein FIG. 9 is a plan view of a portion of the layout of a chromeless PSM in accordance with second preferred embodiment of this invention; FIG. 10 is a schematic, cross-sectional view of the chromeless PSM taken along line I-I of FIG. 9; FIG. 11 is a schematic, cross-sectional view of the chromeless PSM taken along line II-II of FIG. 9; FIG. 12 is a plan view of a portion of the resultant equal line/space dense line pattern transferred from the chromeless PSM of FIG. 9 to a photoresist film in accordance with the second embodiment of this invention.

As shown in FIG. 9, the chromeless PSM in accordance with the second preferred embodiment of this invention comprises a transparent quartz substrate 100, a plurality of first phase-shifting line patterns 102 a-102 f arranged in parallel with each other along the reference Y-axis, and a plurality of second phase-shifting line patterns 104 a-104 e arranged in parallel with each other along the reference Y-axis. According to the second preferred embodiment, the line width of each of the first phase-shifting line patterns 102 a-102 f and the line width of each of the second phase-shifting line patterns 104 a-104 e are the same.

Likewise, the aforesaid first phase-shifting line patterns 102 a-102 f and second phase-shifting line patterns 104 a-104 e are alternately formed on the quartz substrate 100. By way of example, the second phase-shifting line pattern 104 a is disposed between the first phase-shifting line pattern 102 a and the first phase-shifting line pattern 102 b, the second phase-shifting line pattern 104 b is disposed between the first phase-shifting line pattern 102 b and the first phase-shifting line pattern 102 c, and so forth. Besides, along each of the first phase-shifting line patterns 102 a-102 f, a plurality of block areas 106 a-106 f are provided. The block areas are disposed equally spaced apart from each other along each of first phase-shifting line patterns 102 a-102 f. As shown in FIG. 9, for example, a 100%-light transmission first phase-shifting area 108 a is disposed between two adjacent block areas 106 a along the first phase-shifting line pattern 102 a. These block areas are equal in size and have a light transmission rate of about 5%-10%, i.e., merely 5%-10% of the incident light can pass through each of the block areas.

Therefore, the second phase-shifting line patterns 104 a-104 e of the chromeless PSM of this invention are 100% light transmittable. Each of the first phase-shifting line patterns 102 a-102 f of the chromeless PSM encompasses alternating 100% light transmittable clear areas and 5%-10% light transmittable block areas. According to the second preferred embodiment, the length of one side of each of the rectangular 5%-10% light transmittable block areas 106 a-106 f along the reference Y-axis ranges approximately from λ/4 to 3λ/4 (λ: wavelength of the exposure light source of the stepper and scanner in nanometer). The length of one side of each of the rectangular 100% light transmittable clear areas 108 a-108 f along the reference Y-axis ranges approximately from λ/4 to 3λ/4. Each of the block areas 106 a-106 f may be formed from phase shifter such as MoSi, MoSiO, MoSiON or the like.

As shown in FIG. 10 and FIG. 11, the thickness of the quartz substrate 100 underneath each of the first phase-shifting line patterns 102 a-102 f is denoted as t₁, and the thickness of the quartz substrate 100 underneath each of the second phase-shifting line patterns 104 a-104 e is denoted as t₂, wherein t₁is greater than t₂(t₁>t₂), such that light passing through the quartz substrate 100 having different thicknesses produces image contrast. The phase difference between the phase of light passed through the first phase-shifting line patterns 102 a-102 f and the phase of light passed through the second phase-shifting line patterns 104 a-104 e is 180 degree. Preferably, the phase of light passed through the first phase-shifting line patterns 102 a-102 f is 0-degree, while the phase of light passed through the second phase-shifting line patterns 104 a-104 e is 180-degree (π).

According to the second preferred embodiment, the 5%-10% light transmittable block areas on two adjacent first phase-shifting line patterns are not aligned with the reference X-axis. For example, as best seen in FIG. 9, the spaced apart 5%-10% light transmittable block areas 106 a, 106 c, and 106 e, which are disposed on each of the first phase-shifting line patterns 102 a, 102 c, and 102 e, respectively, are aligned with the reference X-axis, while the spaced apart 5%-i 0% light transmittable block areas 106 b, 106 d, and 106 f, which are disposed on each of the first phase-shifting line patterns 102 b, 102 d, and 102 f, respectively, are aligned with the reference X-axis. By providing such improved layout of the chromeless PSM, resultant dense line patterns 302 a-302 f transferred from the chromeless PSM of this invention to a photoresist film coated on a wafer is depicted in FIG. 12. The CD uniformity of the resultant dense line pattern (in equal line/space fashion) is enhanced.

FIG. 13 is a schematic diagram illustrating the CD uniformity of the equal line/space dense line patterns 202 a and 202 b of FIG. 12 according to the second preferred embodiment of this invention. As can be seen in this figure, the variation of the CD of the line pattern 302 a or 302 b is reduced.

Those skilled in the art will readily observe that numerous modifications and alterations of the device and method may be made while retaining the teachings of the invention. Accordingly, the above disclosure should be construed as limited only by the metes and bounds of the appended claims. 

1. A phase-shifting mask (PSM), comprising: a transparent substrate; columns of first phase-shifting line patterns having a first substrate thickness of first phase disposed on the transparent substrate along a first direction, wherein each of the first phase-shifting line patterns is alternately disposed thereon with 100% clear regions of the first phase and 5%-10% light transmittable block areas; and columns of 100% light transmittable second phase-shifting line patterns, in parallel with the first phase-shifting line patterns, having a second substrate thickness of second phase, wherein the first phase-shifting line patterns and second phase-shifting line patterns have the same line width and are alternately disposed on the transparent substrate.
 2. The PSM of claim 1 wherein the 5%-10% light transmittable block areas are equal in size.
 3. The PSM of claim 1 wherein the 5%-i 0% light transmittable block areas are disposed equally spaced apart along each of the first phase-shifting line patterns.
 4. The PSM of claim 1 wherein the 5%-10% light transmittable block areas on odd columns of the first phase-shifting line patterns are aligned with a second direction normal to the first direction, while the 5%-10% light transmittable block areas on even columns of the first phase-shifting line patterns are aligned with the second direction.
 5. The PSM of claim 1 wherein each of the 5%-10% light transmittable block areas has a length along the first direction ranging from λ/4 to 3λ/4 (λ: wavelength of exposure light source of a stepper and scanner).
 6. The PSM of claim 1 wherein each of the 100% clear regions has a length along the first direction ranging from λ/4 to 3λ/4 (λ: wavelength of exposure light source of a stepper and scanner).
 7. The PSM of claim 1 wherein the first substrate thickness is greater than the second substrate thickness such that light that passes through the 100% clear regions of the first phase and light that passes through the 100% light transmittable second phase-shifting line patterns of second phase have a phase difference of 180 degree.
 8. The PSM of claim 1 wherein the transparent substrate is a quartz substrate.
 9. The PSM of claim 1 wherein the 5%-10% light transmittable block areas are made from phase shifter.
 10. The PSM of claim 9 wherein the phase shifter comprises MoSi, MoSiO and MoSiON.
 11. A phase-shifting mask (PSM), comprising: a transparent substrate; a first phase-shifting mesa line pattern having a first substrate thickness of first phase disposed on the transparent substrate, wherein the first phase-shifting mesa line pattern has thereon a clear region of the first phase that is disposed between adjacent 5%-10% light transmittable block areas; and a second phase-shifting recessed line pattern, being in parallel with the first phase-shifting line patterns, having a second substrate thickness of second phase etched into the transparent substrate, wherein the first phase-shifting line pattern and second phase-shifting line pattern have the same line width.
 12. The PSM of claim 11 wherein the 5%-10% light transmittable block areas are equal in size.
 13. The PSM of claim 11 wherein the 5%-10% light transmittable block areas are disposed spaced apart along the first phase-shifting mesa line pattern.
 14. The PSM of claim 11 wherein the each of the 5%-10% light transmittable block areas has a length along the first direction ranging from λ/4 to 3λ/4 (λ: wavelength of exposure light source of a stepper and scanner).
 15. The PSM of claim 11 wherein the clear region of the first phase has a length along the first direction ranging from λ/4 to 3λ/4 (λ: wavelength of exposure light source of a stepper and scanner).
 16. The PSM of claim 1 wherein the first substrate thickness is greater than the second substrate thickness such that light that passes through the 100% clear regions of the first phase and light that passes through the 100% light transmittable second phase-shifting line patterns of second phase have a phase difference of 180 degree.
 17. The PSM of claim 11 wherein the transparent substrate is a quartz substrate.
 18. The PSM of claim 11 wherein the 5%-10% light transmittable block areas are made from phase shifter.
 19. The PSM of claim 18 wherein the phase shifter comprises MoSi, MoSiO and MoSiON. 